Water
|
|
|
|
0.998
|
1.0
|
74.4 (air)
|
|
Gasoline
|
|
|
|
0.71–0.77
|
0.5
|
27 (15°C)
|
|
Diesel fuel
|
|
|
|
0.80–0.85
|
1.1–3.5
|
27 (15°C)
|
|
TCE, pure
|
|
|
100% TCE
|
1.46
|
0.57
|
34.5
|
|
TCE-rich spent vapor degreasing solvent DNAPL at Hill Air Force Base, UT OU2
|
Spent degreasing solvents (mainly TCE) were disposed of in unlined trenches between 1967 and 1975.
|
~41,000 gallons of DNAPL have been pumped from a sand and gravel channel aquifer ~45–50 ft bgs that is underlain by clay. DNAPL sampled from recovery wells was analyzed circa 1994.
|
DNAPL consisted of TCE (53%–60%), TCA (5%–12%), PCE (3%–5%), and other chlorinated degreasing solvents and oil and grease (~25%).
|
1.38
|
0.78
|
9
|
|
TCE degreasing solvent DNAPL (unused) from a metal parts manufacturer in Connecticut (Site A)
|
TCE was apparently released from leaking USTs and product distribution lines between the late 1950s and the early 1970s.
|
DNAPL, which had accumulated at the bottom of a glacial outwash sand aquifer (~30 ft bgs) above a thick clay layer, was pumped from two wells and analyzed in 1996.
|
>99.5% TCE with minor PCE, CCl4, and TCA
|
1.45
|
0.54–0.55
|
21.1–23.5
|
|
PCE, pure
|
|
|
100% PCE
|
1.63
|
0.9
|
44.4
|
|
PCE DNAPL from a dry cleaning facility at Camp Lejeune, NC, Site 88
|
PCE dry cleaning fluid releases occurred between the 1970s and 1995 from leaking USTs, floor drains, and pipes.
|
DNAPL was located adjacent to and beneath the dry cleaning building in fine sand and silt at 17–20 ft bgs just above a clay layer. The analyzed DNAPL sample was pumped from a well in 1997.
|
The reduced density suggests that the PCE DNAPL contained a small fraction of dissolved mineral oils and grease.
|
1.588
|
0.85–1.10
|
10.4
|
|
PCE-rich vapor degreaser solvent DNAPL recovered from a well in shallow alluvium at Kelly Air Force Base, TX
|
Solvents, which leaked from degreasers and piping between the 1940s and 1980s, migrated to and pooled in alluvial deposits at ~40 ft bgs.
|
DNAPL was discovered in 1997 beneath buildings that housed metal plating and degreasing operations. Approximately 1,000 gallons of DNAPL was pumped from the alluvium in 1998.
|
PCE-rich DNAPL
|
1.60
|
0.9
|
14.6
|
|
PCE degreasing solvent DNAPL (unused) from a former plating shop degreaser and a PCE bulk storage tank at the Connecticut ‘B’ Site
|
PCE solvent was apparently released from degreasers and USTs between 1950 and the late 1980s.
|
DNAPL present in fine to coarse sand layers was pumped from two wells in 2003.
|
>99.9% PCE, <0.1% TCE
|
1.62
|
1.11
|
23.6–34.2
|
|
Mixed TCE and PCE vapor-degreasing DNAPL from Site X701B at the USDOE’s Portsmouth Gaseous Diffusion Plant, OH
|
An estimated 80,000 gallons of solvent waste from degreasing and other operations was released to a holding pond between 1953 and 1988.
|
DNAPL migrated into the lower sand and gravel unit of the Gallia Sand at approximately 30 ft bgs. Sample analysis was performed in 1995.
|
Lab analysis of a DNAPL sample indicated three times more TCE than PCE, but contaminant recoveries in the analysis were very low.
|
1.43
|
4
|
NR
|
|
Mixed chemical waste DNAPLs, including chlorobenzenes, chlorophenols, and chlorotoluenes from the Love Canal chemical waste landfill in Niagara Falls, NY
|
An estimated 22,000 tons of chemical plant wastes was deposited in an abandoned canal and pits between 1942 and 1954.
|
DNAPL was sampled from eight wells completed into the buried waste cells in 1988.
|
Lab analyses indicate that the DNAPLs are variable complex multi-component mixtures.
|
1.09–1.50
|
<16–270
|
NR
|
|
Chlorobenzene
|
|
|
100% chlorobenzene
|
1.11
|
0.799
|
37.4
|
|
DNAPL (mixed chlorobenzene and DDT) from the Montrose Chemical Superfund Site, a former DDT manufacturing facility in Los Angeles County, CA
|
Mixed chlorobenzene and DDT DNAPL was released from the Central Processing Area of the Montrose facility, presumably between the 1950s and early 1980s.
|
DNAPL was documented in silt and sand lenses at ~70 ft– 95 ft bgs within an aquitard unit. DNAPL samples were pumped from four wells in 2003.
|
Mixed chlorobenzene and DDT, multicomponent DNAPL
|
1.24–1.25
|
2.5–2.8
|
13–15
|
|
DNAPL (mixed chemicals) from the Casmalia Resources Superfund Site in Santa Barbara County, CA
|
An estimated 5.6 billion pounds of mixed chemical wastes were disposed of in landfills, ponds, trenches, and shallow wells between 1973 and 1989.
|
DNAPL samples were pumped in 2003 to 2004 from wells completed in fractured claystone at ~75–150 ft bgs.
|
Complex mixture of numerous VOCs and SVOCs
|
1.01–1.09
|
3.3–9.7
|
2.8–7.1
|
|
Mixed chlorinated solvent DNAPL (such as PCE or CCl4) from chemical manufacturing releases the at ICI/Orica Botany Bay site, Sydney, Australia
|
An estimated 14 million kg of chlorinated hydrocarbons, including PCE, TCE, 1, 2-DCA, and CCl4, were released in different site areas between 1944 and the 1990s.
|
DNAPL has migrated down through ~90 ft of sand to a clay layer. Samples taken from three wells in the southern plume area were analyzed in 2006.
|
Lab analyses indicate major components of the mixed DNAPL area: PCE (55%–60%), CCl4 (25%–30%), and hexachloroethane (7%–9%).
|
1.6
|
0.63 – 3.8
|
10 - 15
|
|
Creosote wood-preservative DNAPL
|
|
|
|
1.01–1.13
|
20–50
|
NR
|
|
Creosote wood-preservative DNAPL from 17 sites
|
|
|
|
1.065–1.128
|
11.8–57.1
|
19.5–27.8
|
Foster 2013 Personal communication regarding physical property measurements made by Key Environmental, Inc., on DNAPL samples taken from 16 Beazer East, former Koppers, wood-treating and coal tar refining sites in the United States)
|
Weathered creosote DNAPL pumped from seven wells at the Cabot Carbon/Koppers Superfund site, FL
|
Creosote used to preserve utility poles and timbers between 1916 and 1992 was released in lagoon, cooling pond, and drip track areas.
|
Creosote DNAPL has migrated through surficial aquifer sand (~20–25 ft thick) and into the Upper Hawthorne Group clay. DNAPL samples pumped from seven wells were analyzed in 2006.
|
Weathered creosote DNAPL
|
1.02–1.10 (60°C)
|
4.9–25.5 (40°C)
|
17–23
|
|
Former MGP coal tar typical range of data
|
~1850 to 1950
|
Aged releases
|
Aged MGP coal tar
|
1.02–1.1
|
20–100 (but can be much higher)
|
15–27
|
See data and references below
|
Eight former MGP sites
|
Various
|
Sampled in 1989 to 1990
|
Aged MGP coal tar
|
1.06–1.43
|
34–6,600 (40°C)
|
NR
|
|
Spring Gardens Former MGP, Baltimore, MD
|
Operated from 1955 to ~1973
|
Coal tar migrated through mixed fill over clay and was pumped from a well ~18 ft bgs. Analyzed samples were collected from 1988 to 1998.
|
Aged MGP coal tar
|
1.07– 1.1
|
56–126
(100°F)
|
21.1
|
|
NW Natural Gas Co., Former MGP, Portland, OR
|
Former MGP operated from 1915 to 1956; site was also used for coal tar distillation (1965 to 1973) and storage/transfer of creosote and coal tar pitch (post-1977)
|
Samples were collected in 1998 from wells in shallow fill (22–32 ft bgs) and underlying alluvium (30–80 ft bgs).
|
Aged MGP coal tar
|
1.05–1.10
|
72–113
|
14.2–15.8
|
|
Former MGP coal tar, Auburn, NY
|
Operated from 1902 to 1946
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.066
|
63.6
|
26.6
|
|
Former MGP coal tar, Cape May, NJ
|
Operated from 1853 to 1937
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.054
|
51.0
|
22.6
|
|
Former MGP coal tar, Charleston, SC
|
Operated from 1855 to 1957
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.104
|
425.3
|
20.7
|
|
Former MGP coal tar, Fairfield, IA
|
Operated from 1878 to 1950
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.062
|
62.9
|
24.1
|
|
Former MGP coal tar, Portland, OR
|
Operated from 1852 to 1965
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.054
|
34.7
|
NM
|
|
Former MGP coal tar, Saranac, NY
|
Operated from 1896 to 1944
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.062
|
62.9
|
24.1
|
|
Former MGP coal tar, Shippensburg, PA
|
Operated from ~1898 to 1948
|
Sample collected circa 2001
|
Aged MGP coal tar
|
1.076
|
32.0
|
21.9
|
|
Former MGP coal tar, Stroudsburg, PA
|
Operated from ~1880 to 1945
|
Sample collected circa 1982
|
Aged MGP coal tar
|
1.017 (15.5°C)
|
19 (7°C)
|
22
|
|
PCB DNAPLs consisting of variable mixtures of congeners and carrier fluids (for example, chlorobenzenes and mineral oil)
|
|
|
|
1.1–1.5
|
10–50
|
NR
|
|
Creosote 1
|
|
Aged release
|
Aged release
|
1.111
|
74.8
|
38.9
|
|
Creosote 2
|
|
Aged release
|
Aged release
|
1.046
|
95.5
|
35.5
|
|
# 6 fuel oil
|
|
Aged release
|
Aged release
|
1.05
|
2,300
|
~40
|
|
Mixed DNAPL
|
|
17% chlorinated VOCs
|
17% chlorinated VOCs
|
1.05
|
10.4
|
11.6
|
|
Weathered mixed DNAPL
|
|
<0.1 % chlorinated VOCs
|
<0.1 % chlorinated VOCs
|
1.04
|
51.7
|
14.3
|
|
NAPL collected at a MGP
|
|
MGP tar mix
|
MGP tar mix
|
1.03
|
1,389
|
83.75
|
|