Physical properties (density, viscosity, and interfacial tension) of water, select reference fluids, pure NAPLs, and field aged/weathered DNAPLs (including chlorinated solvents, mixed DNAPLs, MGP coal tar, and coal tar creosote). All values were measured at 20° to 25°C unless noted otherwise.

Liquid

Release Source and Age/Date

Sample Source and Date

NAPL Composition

Density
(g/cc-3)

Viscosity (cP)

Interfacial Tension,
Water Interface
(dynes∙cm-1)

References

Water

 

 

 

0.998

1.0

74.4 (air)

 

Gasoline

 

 

 

0.71–0.77

0.5

27
(15°C)

Wang et al. 2006

Diesel fuel

 

 

 

0.80–0.85

1.1–3.5

27
(15°C)

Wang et al. 2006

TCE, pure

 

 

100% TCE

1.46

0.57

34.5

Pankow and Cherry 1996

Cohen et al. 1993

TCE-rich spent vapor degreasing solvent DNAPL at Hill Air Force Base, UT OU2

Spent degreasing solvents (mainly TCE) were disposed of in unlined trenches between 1967 and 1975.

~41,000 gallons of DNAPL have been pumped from a sand and gravel channel aquifer ~45–50 ft bgs that is underlain by clay. DNAPL sampled from recovery wells was analyzed circa 1994.

DNAPL consisted of TCE (53%–60%), TCA (5%–12%), PCE (3%–5%), and other chlorinated degreasing solvents and oil and grease (~25%).

1.38

0.78

9

Oolman et al. 1995

Jackson and Dwarakanath 1999

Meinardus et al. 2000

Dwarakanath et al. 2002

USAF 2009

TCE degreasing solvent DNAPL (unused) from a metal parts manufacturer in Connecticut (Site A)

TCE was apparently released from leaking USTs and product distribution lines between the late 1950s and the early 1970s.

DNAPL, which had accumulated at the bottom of a glacial outwash sand aquifer (~30 ft bgs) above a thick clay layer, was pumped from two wells and analyzed in 1996.

>99.5% TCE with minor PCE, CCl4, and TCA

1.45

0.54–0.55

21.1–23.5

Parker et al. 2003

Chapman and Parker 2005

PCE, pure

 

 

100% PCE

1.63

0.9

44.4

Pankow and Cherry 1996

Cohen et al. 1993

PCE DNAPL from a dry cleaning facility at Camp Lejeune, NC, Site 88

PCE dry cleaning fluid releases occurred between the 1970s and 1995 from leaking USTs, floor drains, and pipes.

DNAPL was located adjacent to and beneath the dry cleaning building in fine sand and silt at 17–20 ft bgs just above a clay layer. The analyzed DNAPL sample was pumped from a well in 1997.

The reduced density suggests that the PCE DNAPL contained a small fraction of dissolved mineral oils and grease.

1.588

0.85–1.10

10.4

Duke Engineering & Services 1999

Dwarakanath et al. 2002

PCE-rich vapor degreaser solvent DNAPL recovered from a well in shallow alluvium at Kelly Air Force Base, TX

Solvents, which leaked from degreasers and piping between the 1940s and 1980s, migrated to and pooled in alluvial deposits at ~40 ft bgs.

DNAPL was discovered in 1997 beneath buildings that housed metal plating and degreasing operations. Approximately 1,000 gallons of DNAPL was pumped from the alluvium in 1998.

PCE-rich DNAPL

1.60

0.9

14.6

USEPA 2000

Dwarakanath et al. 2002

PCE degreasing solvent DNAPL (unused) from a former plating shop degreaser and a PCE bulk storage tank at the Connecticut ‘B’ Site

PCE solvent was apparently released from degreasers and USTs between 1950 and the late 1980s.

DNAPL present in fine to coarse sand layers was pumped from two wells in 2003.

>99.9% PCE, <0.1% TCE

1.62

1.11

23.6–34.2

Parker et al. 2003

Mixed TCE and PCE vapor-degreasing DNAPL from Site X701B at the USDOE’s Portsmouth Gaseous Diffusion Plant, OH

An estimated 80,000 gallons of solvent waste from degreasing and other operations was released to a holding pond between 1953 and 1988.

DNAPL migrated into the lower sand and gravel unit of the Gallia Sand at approximately 30 ft bgs. Sample analysis was performed in 1995.

Lab analysis of a DNAPL sample indicated three times more TCE than PCE, but contaminant recoveries in the analysis were very low.

1.43

4

NR

Young et al. 1999

Mixed chemical waste DNAPLs, including chlorobenzenes, chlorophenols, and chlorotoluenes from the Love Canal chemical waste landfill in Niagara Falls, NY

An estimated 22,000 tons of chemical plant wastes was deposited in an abandoned canal and pits between 1942 and 1954.

DNAPL was sampled from eight wells completed into the buried waste cells in 1988.

Lab analyses indicate that the DNAPLs are variable complex multi-component mixtures.

1.09–1.50

<16–270

NR

Cohen et al. 1993

Chlorobenzene

 

 

100% chlorobenzene

1.11

0.799

37.4

Mercer and Cohen 1990

DNAPL (mixed chlorobenzene and DDT) from the Montrose Chemical Superfund Site, a former DDT manufacturing facility in Los Angeles County, CA

Mixed chlorobenzene and DDT DNAPL was released from the Central Processing Area of the Montrose facility, presumably between the 1950s and early 1980s.

DNAPL was documented in silt and sand lenses at ~70 ft– 95 ft bgs within an aquitard unit. DNAPL samples were pumped from four wells in 2003.

Mixed chlorobenzene and DDT, multicomponent DNAPL

1.24–1.25

2.5–2.8

13–15

Hargis and Associates 2004

Davis and Hayworth 2006

DNAPL (mixed chemicals) from the Casmalia Resources Superfund Site in Santa Barbara County, CA

An estimated 5.6 billion pounds of mixed chemical wastes were disposed of in landfills, ponds, trenches, and shallow wells between 1973 and 1989.

DNAPL samples were pumped in 2003 to 2004 from wells completed in fractured claystone at ~75–150 ft bgs.

Complex mixture of numerous VOCs and SVOCs

1.01–1.09

3.3–9.7

2.8–7.1

Casmalia Resources Site Steering Committee 2011

Mixed chlorinated solvent DNAPL (such as PCE or CCl4) from chemical manufacturing releases the at ICI/Orica Botany Bay site, Sydney, Australia

An estimated 14 million kg of chlorinated hydrocarbons, including PCE, TCE, 1, 2-DCA, and CCl4, were released in different site areas between 1944 and the 1990s.

DNAPL has migrated down through ~90 ft of sand to a clay layer. Samples taken from three wells in the southern plume area were analyzed in 2006.

Lab analyses indicate major components of the mixed DNAPL area: PCE (55%–60%), CCl4 (25%–30%), and hexachloroethane (7%–9%).

1.6

0.63 – 3.8

10 - 15

Golder and Associates 2011

Creosote wood-preservative DNAPL

 

 

 

1.01–1.13

20–50

NR

Kueper et al. 2003

Creosote wood-preservative DNAPL from 17 sites

 

 

 

1.065–1.128

11.8–57.1

19.5–27.8

Foster 2013 Personal communication regarding physical property measurements made by Key Environmental, Inc., on DNAPL samples taken from 16 Beazer East, former Koppers, wood-treating and coal tar refining sites in the United States)

Weathered creosote DNAPL pumped from seven wells at the Cabot Carbon/Koppers Superfund site, FL

Creosote used to preserve utility poles and timbers between 1916 and 1992 was released in lagoon, cooling pond, and drip track areas.

Creosote DNAPL has migrated through surficial aquifer sand (~20–25 ft thick) and into the Upper Hawthorne Group clay. DNAPL samples pumped from seven wells were analyzed in 2006.

Weathered creosote DNAPL

1.02–1.10 (60°C)

4.9–25.5
(40°C)

17–23

Mercer et al. 2006

Former MGP coal tar typical range of data

~1850 to 1950

Aged releases

Aged MGP coal tar

1.02–1.1

20–100 (but can be much higher)

15–27

See data and references below

Eight former MGP sites

Various

Sampled in 1989 to 1990

Aged MGP coal tar

1.06–1.43

34–6,600 (40°C)

NR

Lee et al. 1992

EPRI 1993

Spring Gardens Former MGP, Baltimore, MD

Operated from 1955 to ~1973

Coal tar migrated through mixed fill over clay and was pumped from a well ~18 ft bgs. Analyzed samples were collected from 1988 to 1998.

Aged MGP coal tar

1.07– 1.1

56–126

(100°F)

21.1

EPRI 2000

NW Natural Gas Co., Former MGP, Portland, OR

Former MGP operated from 1915 to 1956; site was also used for coal tar distillation (1965 to 1973) and storage/transfer of creosote and coal tar pitch (post-1977)

Samples were collected in 1998 from wells in shallow fill (22–32 ft bgs) and underlying alluvium (30–80 ft bgs).

Aged MGP coal tar

1.05–1.10

72–113

14.2–15.8

Hahn & Assoc. Inc. 2007

Former MGP coal tar, Auburn, NY

Operated from 1902 to 1946

Sample collected circa 2001

Aged MGP coal tar

1.066

63.6

26.6

Kong 2004

EPRI 2004

Former MGP coal tar, Cape May, NJ

Operated from 1853 to 1937

Sample collected circa 2001

Aged MGP coal tar

1.054

51.0

22.6

Kong 2004

EPRI 2004

Former MGP coal tar, Charleston, SC

Operated from 1855 to 1957

Sample collected circa 2001

Aged MGP coal tar

1.104

425.3

20.7

Kong 2004

EPRI 2004

Former MGP coal tar, Fairfield, IA

Operated from 1878 to 1950

Sample collected circa 2001

Aged MGP coal tar

1.062

62.9

24.1

Kong 2004

EPRI 2004

Former MGP coal tar, Portland, OR

Operated from 1852 to 1965

Sample collected circa 2001

Aged MGP coal tar

1.054

34.7

NM

Kong 2004

EPRI 2004

Former MGP coal tar, Saranac, NY

Operated from 1896 to 1944

Sample collected circa 2001

Aged MGP coal tar

1.062

62.9

24.1

Kong 2004

EPRI 2004

Former MGP coal tar, Shippensburg, PA

Operated from ~1898 to 1948

Sample collected circa 2001

Aged MGP coal tar

1.076

32.0

21.9

Kong 2004

EPRI 2004

Former MGP coal tar, Stroudsburg, PA

Operated from ~1880 to 1945

Sample collected circa 1982

Aged MGP coal tar

1.017
(15.5°C)

19
(7°C)

22

Villaume 1985

PCB DNAPLs consisting of variable mixtures of congeners and carrier fluids (for example, chlorobenzenes and mineral oil)

 

 

 

1.1–1.5

10–50

NR

Kueper et al. 2003

Creosote 1

 

Aged release

Aged release

1.111

74.8

38.9

 

Creosote 2

 

Aged release

Aged release

1.046

95.5

35.5

 

# 6 fuel oil

 

Aged release

Aged release

1.05

2,300

~40

 

Mixed DNAPL

 

17% chlorinated VOCs

17% chlorinated VOCs

1.05

10.4

11.6

 

Weathered mixed DNAPL

 

<0.1 % chlorinated VOCs

<0.1 % chlorinated VOCs

1.04

51.7

14.3

 

NAPL collected at a MGP

 

MGP tar mix

MGP tar mix

1.03

1,389

83.75

 

°C = degrees Celsius
°F = degrees Fahrenheit
bgs = below ground surface
DCA = dichloroethane
ft = feet

g = grams
kg = kilograms


NM = not measured
NR = not recorded
s = seconds
SVOC = semivolatile organic compound
TCA = trichloroethane
USDOE = U.S. Department of Energy
UST = underground storage tank
VOC = volatile organic compound